Micro-Raman Spectroscopy Laboratory

The Micro-Raman Spectroscopy Laboratory (Sections 3.1 and 3.2) uses a Horiba Jobin Yvon LabRAM HR Evolution Raman spectrometer equipped with a motor-driven x-y table and an Olympus optical microscope. Depending on the experiment two different laser light sources can be used for investigations on gas hydrates: a Nd:YAG laser providing a 532 nm line and 785 nm wavelength-stabilized laser diode. The confocal technique provides an efficient way to obtain interference-free Raman spectra of specimens embedded in transparent matrix (grain mounts, thin sections) but also for gas hydrate crystals.

Application of Raman spectroscopy in earth sciences:

• identification of mineral phases
• composition of the gas phase in fluid and melt inclusions (qualitative and semi-quantitative)
• detection of anions in fluid inclusions (CO₃²⁻, HCO₃⁻, PO₄³⁻, BO₄³⁻, SO₄²⁻, HS⁻, OH⁻)
• identification of crystalline dimorphs and polymorphs (e.g., calcite-aragonite; sillimanite- kyanite- andalusite)
  
  

Applications in gas hydrate research:

• determination of the composition of gas hydrates (qualitative and semi-quantitative) during formation, growth and equilibrium state
• determination of hydrate structure and cage occupancies
• investigation on hydrate formation kinetics
• mapping of natural and synthesized samples
• determination of co-existing phases
  
  

For Raman studies at ambient pressure and temperatures between -196 °C and 1500 °C we use LINKAM stages. For Raman spectroscopic investigation of gas hydrates we use a custom made pressure cell with a volume of about 400 µl which can be used at pressures up to 10 MPa and in the temperature range between -30 °C and about 60 °C.